‘Ionic crystals’ consisting of trinuclear macrocations and polyoxometalate anions exhibiting single crystal to single crystal transformation: breathing of crystals

Author:

Arumuganathan T,Siddikha Asha,Das Samar KORCID

Funder

Science and Engineering Research Board

Publisher

Springer Science and Business Media LLC

Subject

General Chemistry

Reference34 articles.

1. Vlachos A, Psycharis V, Raptopoulou C P, Lalioti N, Sanakis Y, Diamantopoulos G, Fardis M, Karayanni M, Papavassiliou G and Terzis A 2004 A nearly symmetric trinuclear chromium(III) oxo carboxylate assembly: preparation, molecular and crystal structure, and magnetic properties of [ $$\text{Cr}_{3}\text{ O }(\text{ O }_{2}\text{ CPh })_{6}(\text{ MeOH })_{3}$$ Cr 3 O ( O 2 CPh ) 6 ( MeOH ) 3 2MeOH Inorg. Chim. Acta 357 3162

2. Fujihara T, Aonahata J, Kumakura S, Nagasawa A, Murakami K and Ito T 1998 Kinetic Study on the Substitution of Dimethylacetamide for the Terminal Aqua Ligands in the Trinuclear Chromium(III) Complexes [ $$\text{ Cr }_{3}(\mu _{3}$$ Cr 3 ( μ 3 -O)( $$\mu -RCO_{2})6(\text{ H }_{2}\text{ O })_{3}]^{+}$$ μ - R C O 2 ) 6 ( H 2 O ) 3 ] + (R) H, $$\text{ CH }_{3}$$ CH 3 , $$\text{ CH }_{3}\text{ CH }_{2}$$ CH 3 CH 2 , $$\text{ CH }_{2}$$ CH 2 Cl, $$\text{ CHCl }_{2}$$ CHCl 2 , $$\text{ CH }_{3}\text{ OCH }_{2}$$ CH 3 OCH 2 , $$(\text{ CH }_{3})_{3}$$ ( CH 3 ) 3 C, $$\text{ CH }_{2}\text{ ClCH }_{2}$$ CH 2 ClCH 2 , ( $$\text{ CH }_{3}\text{ CH }_{2})_{2}$$ CH 3 CH 2 ) 2 CH). Elucidation of the Mechanism from the Activation Volumes and the Substituent Effects of Bridging Carboxylate Ligands Inorg. Chem. 37 3779

3. Anson C E, Bourke J P, Cannon R D, Jayasooriya U A, Molinier M and Powell A K 1997 Crystal Structures of the Isomorphous Prototypic Oxo-Centered Trinuclear Complexes [ $$\text{ Cr }_{3}\text{ O }(\text{ OOCCH }_{3})_{6}(\text{ H }_{2}\text{ O })_{3}]\text{ Cl }\cdot 6\text{ H }_{2}$$ Cr 3 O ( OOCCH 3 ) 6 ( H 2 O ) 3 ] Cl · 6 H 2 O and [ $$\text{ Fe }_{3}\text{ O }(\text{ OOCCH }_{3})_{6}(\text{ H }_{2}\text{ O })_{3}]\text{ Cl }\cdot 6\text{ H }_{2}\text{ O }$$ Fe 3 O ( OOCCH 3 ) 6 ( H 2 O ) 3 ] Cl · 6 H 2 O  Inorg. Chem. 36 1265

4. Cannon R D, Jayasooriya U A, Sowrey F E, Tilford C, Little A, Bourke J P, Rogers R D, Vincent J B and Kearley G J 1998 Concealed Asymmetry in an Exchange-Coupled Trichromium(III) Cluster: Structure and Magnetic Spectrum of [ $$\text{ Cr }_{3}\text{ O }(\text{ OOCPh })_{6}(\text{ py })_{3}](\text{ py })_{0.5}\text{ ClO } _{4}$$ Cr 3 O ( OOCPh ) 6 ( py ) 3 ] ( py ) 0.5 ClO 4  Inorg. Chem. 37 5675

5. Keeney L and Hynes M J 2005 Kinetics and mechanisms of the electron transfer reactions of oxo-centred carboxylate bridged complexes, [ $$\text{ Fe }_{3}(\mu _{3}-O)(\text{ O }_{2}\text{ CR })_{6}\text{ L }_{3}]\text{ ClO }_{4}$$ Fe 3 ( μ 3 - O ) ( O 2 CR ) 6 L 3 ] ClO 4 , with verdazyl radicals in acetonitrile solution Dalton Trans. 1524

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