Preparation of new modified silica gel terminated with phenylphosphonic acid-amide moieties for adsorption of uranium(VI) from aqueous solutions

Author:

Ammar HudaORCID,Shaaban A. F.,Lasheen T. A.,Nouh El Said A.

Abstract

AbstractPAMAM dendrimers modified silica gel terminated phenylphosphonic acid-amide moieties (Si-6G PAMAM-PPAAM) was prepared for uranium(VI) adsorption from aqueous solutions by batch and fixed-bed column methods. The experimental results showed that the maximum capacity was 434.78 mg g−1. Equilibrium isotherm data obeyed Langmuir isotherm model. Kinetic adsorption followed pseudo-second order model and thermodynamic parameters implied the adsorption was spontaneous, endothermic. The adsorption performance of the new adsorbent toward uranium using fixed-bed column method was also investigated. The investigated adsorbent (Si-6G PAMAM-PPAAM) was successfully used to extract uranium from leach liquor of granitic rock sample.

Publisher

Springer Science and Business Media LLC

Subject

Health, Toxicology and Mutagenesis,Public Health, Environmental and Occupational Health,Spectroscopy,Pollution,Radiology, Nuclear Medicine and imaging,Nuclear Energy and Engineering,Analytical Chemistry

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