Author:
Rudolph Wolfram W.,Irmer Gert
Abstract
AbstractThe totally symmetric stretching mode $$\nu_{1}$$ν1 Ln–(OH2) of the first hydration shells of all the rare earth (RE) ions across the series from lanthanum to lutetium has been measured on dilute aqueous perchlorate solutions at room temperature. An S-shaped relationship has been found between the $$\nu_{1}$$ν1 Ln–(OH2) peak positions and the Ln–(OH2) bond distances of the lanthanide(III) aqua ions. While the light rare earth ions form nona-hydrates, the heavy ones form octa-hydrates and the rare earth ions in the middle of the series show non integer hydration numbers between 9 and 8. A relationship between wavenumber positions $$\nu_{1}$$ν1 Ln–(OH2) and the Ln–(OH2) bond distances of the RE hydrates has been given. Recent quantum mechanical calculations support the given interpretation.
Publisher
Springer Science and Business Media LLC
Subject
Physical and Theoretical Chemistry,Molecular Biology,Biochemistry,Biophysics
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