Author:
Huo Fuyang,Zhang Hua,Chen Zhuo,Qiu Ling,Liu Jialei,Bo Shuhui,Kityk I. V.
Abstract
AbstractTwo principally novel chromophores A, B based on fluorene electron donor were synthesized and explored by 1H NMR, 13C NMR, and MS spectra. The delocalized energy levels have been estimated by UV–Vis absorption spectra. The principal innovation consists in modification by addition of amino group. The titled materials have demonstrated a high solubility in common organic solvents, good compatibility with polymers. The maximally achieved electro-optic efficiency of the poled film possessing 25 wt% of A doped in PMMA (25 wt% A/PMMA) achieved a value of 18 pm/V at wavelength 1310 nm, and 25 wt% B/PMMA possessed an electrooptical coefficient equal to 43 pm/V. This one open a perspective of their direct application in optoelectronic telecommunication devices for laser light modulation.
Publisher
Springer Science and Business Media LLC
Subject
Electrical and Electronic Engineering,Condensed Matter Physics,Atomic and Molecular Physics, and Optics,Electronic, Optical and Magnetic Materials
Reference30 articles.
1. J.W. Kang, T.D. Kim, J. Luo, M. Haller, A.K.Y. Jen, Very large electro-optic coefficients from in situ generated side-chain nonlinear optical polymers. Appl. Phys. Lett. 87(7), 071109 (2005)
2. I. Fuks-Janczarek, I.V. Kityk, R. Miedzinski, E. Gondek, J. Ebothe, I. Nzoghe-Mendome, A. Danel, Push-pull benzoxazole based stilbenes as new promising electrooptics materials. J. Mater. Sci.: Mater. Electron. 18, 519–526 (2007)
3. R. Tang, Z. Li, Second-order nonlinear optical dendrimers and dendronized hyperbranched polymers. Chem. Rec. 17(1), 71–89 (2017)
4. J. Liu, G. Xu, F. Liu, I. Kityk, X. Liu, Z. Zhen, Recent advances in polymer electro-optic modulators. RSC Adv. 5(21), 15784–15794 (2015)
5. G.Y. Xu, Z.F. Liu, J. Ma, B.Y. Liu, S.T. Ho, L. Wang, P.W. Zhu, T.J. Marks, J.D. Luo, A.K.Y. Jen, Organic electro-optic modulator using transparent conducting oxides as electrodes. Opt. Express 13(19), 7380–7385 (2005)
Cited by
28 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献